Site of National Interest (SIN), Torviscosa (Udine), Friuli-Venezia Giulia, Italy

Caffaro di Torviscosa (formerly Grado and Marano Lagoon)

A chemical complex that grew from the 1930s around SNIA Viscosa, with a mercury-cell chlor-alkali plant and internal dumps of pyrite cinders, pitches and other residues. It is one of the few Italian sites where phytoremediation was tested for years in the field, directly on pyrite cinders.

Phytoremediation

At a glance

Area
201 ha on land1
Activity
since 1937
People affected
2,710 (2019)2
Media
soil, groundwater, sediment
Kind of site
chemical works, landfill
  1. Area. The first perimeter (decree of 24 February 2003) covered about 10,695 ha, 3,755 on land and 6,940 of lagoon. The decree of 12 December 2012 cut it down to the Caffaro areas, the Valletta landfill and the Banduzzi canals; the decree of 31 March 2017 changed the name and redrew the perimeter (201 ha according to ISPRA, 2024).
  2. People affected. Residents of the municipality of Torviscosa, 2019 census (SENTIERI, Sixth Report).

Contaminants

Status

Remediation under way

Soil: 100% characterised, remediation project approved for 8%, procedure concluded for less than 1%. Groundwater: 100% characterised, project approved for 6%, concluded for less than 1% (ISPRA, June 2024). Between May 2024 and 2025 the Consorzio di Bonifica Pianura Friulana permanently secured two internal landfills; no area has yet been certified as remediated (MASE data of June 2025 quoted by Legambiente, 2026).

Story

Torviscosa is a company town built between 1937 and 1942 around the SNIA Viscosa works, which made cellulose and man-made fibres such as rayon. In the 1950s Caffaro, a SNIA group company, started the chlor-alkali plant; a coal-fired power station followed in 1961. Part of the complex is still working: Caffaro Industrie makes chemical intermediates and a new membrane chlor-alkali plant has run since 2017.

Decades of waste remain inside and next to the works: an area south of the dock long used as a dump, a pitch deposit, two dredging-spoil basins along the Banduzzi canal and the Valletta landfill, 7 km away at the confluence of the Ausa and Corno rivers. The soil holds metals, hydrocarbons, BTEX, PAHs, dioxins and furans, PCBs and aromatic amines; the groundwater also chlorinated aliphatics; the sediments of the Banduzzi canals hold mercury from the chlor-alkali plant. The pyrite cinders, left over from roasting ore to obtain sulphur, contain arsenic, copper, zinc, lead, cadmium and cobalt.

The site was listed in 2001 as "Laguna di Grado e Marano", and in 2003 its perimeter took in 60% of the lagoon. From 2002 a government commissioner worked mainly on sediment characterisation and on dredging for navigation. In 2012 the lagoon was taken out of the perimeter: most of the mercury in its sediments comes from the Idrija mining district, by way of the Isonzo river, while Caffaro's contribution is local. Since 2017 the site has carried the name of the plant.

The programme agreement signed on 28 October 2020 by the Ministry and the Region is worth 48.7 million euros and covers removal of the pitches, restoration of the hydraulic barrier and permanent securing of the landfills. Since 2024 the works have been run by the Consorzio di Bonifica Pianura Friulana, which in 18 months covered 67,000 m² of landfill with an impermeable layer.

Timeline

  1. 1937SNIA Viscosa sets up at Torre di Zuino; the town of Torviscosa is built (1937–1942).
  2. 1961The coal-fired power station is built; the Caffaro chlor-alkali plant had started in the 1950s.
  3. 2001Ministerial Decree 468/2001 lists the 'Laguna di Grado e Marano' Site of National Interest.
  4. 2002The first emergency commissioner is appointed (ordinance 3217 of 3 June).
  5. 2012The decree of 12 December cuts the perimeter down to the Caffaro areas, the Valletta landfill and the Banduzzi canals.
  6. 2017The site is renamed 'Caffaro di Torviscosa'; the new membrane chlor-alkali plant starts up.
  7. 202028 October: programme agreement between Ministry and Region, worth 48.7 million euros.
  8. 2024From May the Consorzio di Bonifica Pianura Friulana starts permanently securing the landfills.

Health

SENTIERI, Sixth Report (mortality 2013–2017, hospital admissions 2014–2018; a single municipality, 2,710 residents): estimates are uncertain because events are few. Among men there is excess mortality from stomach cancer, based on 5 cases, and excess admissions for diseases of the digestive system, in children too. The report notes that the arsenic found in soil and groundwater is a possible risk factor for gastric cancer. Outside the present perimeter, a 2025 study quoted by Legambiente measured a median mercury level of 2.56 mg/kg in fishermen at Marano Lagunare, slightly above the 2 mg/kg recommended by WHO.

Remediation

  1. 2007dredgingDredging of critical stretches of the lagoon channels by the commissioner's office (2007–2008), for safe navigation.
  2. 2024cappingPermanent securing of two internal landfills: 67,000 m² covered with an impermeable layer, with a rainwater drainage network (May 2024 – 2025).
  3. 2024hydraulic barrier, waste removalPlanned under the programme agreement and under way: restoration of the hydraulic barrier and removal of the benzoic pitches.

Plants and fungi at this site

PhytoremediationField scale

Populus spp., Salix spp.

Pot and field trials by the University of Padua on a 0.7 m layer of pyrite cinders capped with 0.15 m of unpolluted gravelly soil. Poplars and willows were compared under two tillage systems, ploughing and subsoiling to 0.35 m, measuring growth and trace-element uptake.

Outcome Above-ground growth was impaired and translocation low: phytoextraction was not feasible and differences between species were marginal. Coarse and fine roots proliferated in the surface layers and acted as a sink for the elements: the authors point to phytostabilisation, with soil amelioration, as the realistic goal.

PhytoremediationField scale

Helianthus annuus, Medicago sativa, Raphanus sativus var. oleiformis, Lolium multiflorum

Sunflower, alfalfa, fodder radish and Italian ryegrass grown in the field on pyrite cinders capped with 0.15 m of clean soil, comparing ploughing with subsoiling to 0.3 m. Ploughing brought about 30% more contamination into the topsoil.

Outcome Removal in the shoots was poor: at most 33 mg/m² of trace elements, 62% of it zinc and 18% copper. Fodder radish and sunflower gave the most biomass. Fine roots in the shallow layers were a large sink for the elements, useful for phytostabilisation.

PhytoremediationGreenhouse, with soil from the site

Raphanus sativus var. oleiformis, Brassica carinata

Pot trials of assisted phytoextraction on the pyrite cinders: indolebutyric acid (IBA) on fodder radish, sprayed on leaves or added to the substrate, and the biodegradable chelator EDDS on Brassica carinata. A 2014 review by the same group sums up ten years of trials with field crops at Torviscosa, including auxins, humic acids and chelators.

Outcome IBA in the substrate cut biomass (roots −59%) and removal, and increased metal leaching. EDDS raised shoot concentrations, copper above all, but stunted growth and left copper more available in the substrate (up to +67%). Over ten years the highest removal was 8 kg/ha of metals, with rapeseed.

PhytoremediationField scale, 2005

Sorghum bicolor, Helianthus annuus

The University of Udine (Marchiol, Fellet, Perosa, Zerbi) grew sorghum and sunflower in randomised blocks on soil with As 309, Cd 4.29, Co 50.9, Cu 1,527 and Zn 980 mg/kg, comparing mineral fertiliser, organic amendment and a control, with relief irrigation.

Outcome Fertiliser and amendment raised biomass a great deal but not the metal concentration in the harvested tissue; in some cases organic matter made the elements less available. Zinc removal was about 2,000 g/ha with sorghum and 1,000 g/ha with sunflower: small amounts against what the soil holds.

From the literature

Species that acted on one of this site's contaminants in at least one study. The list is automatic and takes no account of this site's soil, concentrations or climate.

Plants

Fungi

The rest are on the contaminant pages.

Nearby

Sources

  1. Siti contaminati di interesse nazionale (indicatore, dati a giugno 2024), ISPRA, 2024
  2. Riferimenti normativi per i SIN (aggiornamento 31 dicembre 2025), ISPRA, 2025
  3. Ecogiustizia subito, seconda edizione: scheda SIN Caffaro di Torviscosa, Legambiente, 2026
  4. SENTIERI. Sesto Rapporto. Epidemiologia & Prevenzione 47(1-2) Suppl. 1: risultati Nord-Est (Caffaro di Torviscosa), Istituto Superiore di Sanità / Epidemiologia & Prevenzione, 2023
  5. Vamerali T. et al. Phytoremediation trials on metal- and arsenic-contaminated pyrite wastes (Torviscosa, Italy). Environmental Pollution 157, Elsevier, 2009

Draft compiled from public sources, not yet reviewed.